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3-monoiodothyronine monoiodinated thyronine deiodinase deiodination thyroid hormone human propanoic acid iodotyrosine diiodothyronine diiodo tyrosine gland compound 3d rendering chemistry chemical molecule molecular structural structure formula hormonal therapy replacement function action endocrine level iodine hypothyroidism hyperthyroidism thyromimetic thermogenesis metabolite metabolism biosynthesis pathway path biosynthetic intermediate substrate precursor bioprecursor