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3-methylbutanoic acid delphinic 3-methylbutyric isopentanoic isovaleric alkyl carboxylic short-chain fatty unpleasant odor naturally food valerian valeriana officinalis isomer hydroformylation syngas isovaleraldehyde smell perfumery flavor brettanomyces substance matter material compound component agent stuff reagent functional group precursor synthesis reaction production building block molecule molecular formula skeletal structural structure geometry ball stick additive adjuvants ingredient 3d chemical