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glucose blood sugar dextrose corn d-glucose grape gluco-hexose monosaccharide carbohydrate 3d synthesis entner-doudoroff pathway isomerisation structure glycogen respiratory chain molecule organisms biosynthesis aerobic respiration metabolite citric acid cycle mechanism oxidative decarboxylation derivative enzyme substrate cori stereoisomer amylopectin dextrorotatory bioprecursor skeletal furanose molecular path metabolism structural formula metabolic endogenous pentose phosphate intermediate cellulose contractor open-chain form catabolism biomolecule