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glucose 6-phosphate d-glucopyranose g6p robison ester metabolite metabolism biosynthesis cycle mechanism pathway path catabolism biosynthetic intermediate biogenesis substrate precursor synthesis derivative bioprecursor metabolic enzyme endogenous contractor phosphorylated cells glucose cellular chemistry metabolic pathways glycolysis pentose phosphate glycogen starch nadph nadp dephosphorylation molecule molecular formula skeletal structural structure geometry cell biology biochemistry biomolecule bioactive 3d