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thiirane thiacyclopropane ethylene sulfide cyclic c2h4s heterocycle episulfide organosulfur unpleasant odour electron diffraction kscn mercaptoethylation periodate flammable bleve dangerous fire exothermic reaction poison venom toxicant toxic toxicity toxin toxicology poisoning danger hazard substance compound component agent reagent precursor synthesis production building block molecule molecular formula skeletal structural structure research organic chemical 3d