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rubierythric acid madder dye rubia tinctorum extract derivative alizarin disaccharide bioside 3d food additive traditional chinese medicine pathway structure geometry herbal catabolism skeletal pharmacopoeia coumarin intermediate natural phytotherapy cell biosynthetic monoterpenoid biological activity anti-aging path flavone essential oils isoflavone plant cycle phytochemical structural terpenoid biology phytoalexin bioactive nutrient parasympathomimetic herbalism monoterpene biosynthesis molecular formula flavonoid biochemistry mechanism