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oxetene 1-oxacyclobut-2-ene 2h-oxete unsaturated photochemical cyclization acrolein aromatic aromaticity macrocyclic heterocyclic heterocycle polycyclic ring substance matter material compound component agent stuff reagent functional group precursor synthesis reaction production building block molecule molecular formula skeletal structural structure geometry ball stick chemistry science scientific research organic chemical 3d isolated white background model iupac nomenclature name