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methionine 2-amino-4- methylthio butanoic acid met essential amino cysteine taurine sam-e antioxidant glutathione health metabolite metabolism biosynthesis cycle mechanism pathway path catabolism biosynthetic intermediate biogenesis precursor synthesis derivative bioprecursor metabolic endogenous encoded angiogenesis blood vessels copper poisoning dna methylation cancer protein polypeptide mrna translation proteinogenic sulfur-containing redox sensor ribosome kozak consensus sequence post-translational modification s-adenosyl-methionine trans-sulfurylation regeneration reverse-transulfurylation ethylene dietary