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taurochenodeoxycholic acid 12-deoxycholyltaurine 12-desoxycholyltaurine chenodeoxycholoyltaurine chenodeoxycholyltaurine chenyltaurine taurochenodeoxycholate taurochenodesoxycholic bile liver chenodeoxycholic taurine bile ph ileum cholagogue choleretic epimer perfluorooctanesulfonic taurodeoxycholic metabolite metabolism biosynthesis cycle mechanism biosynthetic intermediate biogenesis substrate precursor synthesis derivative bioprecursor metabolic enzyme endogenous biochemistry biomolecule bioactive biochemical molecule molecular formula skeletal structural structure 3d