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rutinose disaccharide flavonoid glycoside flavonoid rutin hydrolysis rhamnodiastase enzyme rutoside quercetin-3-o-rutinoside sophorin flavonol quercetin citrus ruta graveolens carpobrotus edulis rendering supplement biological activity bioactive nutrient prescription drug food additive nutraceutica dietary antioxidant anti-cancer anti-aging healthy aging alternative medicine tcm traditional chinese herbal herbal phytochemical phytotherapy plant herb natural herbalism pharmacognosy pharmacopoeia cell biochemistry biomolecule biology