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piperonal black pepper oil heliotropin fragrances flavors aromatic aldehydes heliotropine piperonyl aldehyde protocatechuic aldehyde methylene ether methylenedioxybenzaldehyde benzaldehyde vanillin dill vanilla violet flowers pepper synthesis reactions cherry artificial heliotrope acetate mdma safrole isosafrole aroma smell flavor flavour fragrance odor odorant perfume bouquet redolence relish scent goodscent good nuances substance matter material compound component precursor reaction production 3d