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n-methylcytisine methylcytisine alkaloid thermopsis lanceolata sophora chrysophylla caulophylline caulophyllin 3d traditional chinese medicine tcm mechanism molecule antioxidant isoflavone metabolite bioactive cycle biomolecule food additive phytotherapy phytochemical phytoalexin terpene flavonoid parasympathomimetic biology catabolism dietary skeletal herbal formula healthy aging intermediate herb terpenoid anti-aging molecular natural pathway herbal herbalism plant pharmacognosy structure biosynthetic pharmacopoeia cell