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3d 4-isopropenylcyclohex-1-enecarboxylic 4-prop-1-en-2-ylcyclohexene-1-carboxylic acid agent antineoplastic atom ball bioactive biochemical biochemistry biogenesis biology biomolecule bioprecursor biosynthesis biosynthetic catabolism cell contractor cycle cyclohexenecarboxylic database derivative endogenous enzyme formula frutescens geometry hmdb homo human intermediate mechanism metabolic metabolism metabolite metabolome molecular molecule monocarboxylic path pathway perilla perillate perillic perillicacid precursor sapiens skeletal stick structural structure substrate synthesis