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herniarin methoxy derivative coumarin umbelliferone herniaria glabra ayapana triplinervis prunus 7-o-methylumbelliferone 7-methoxycoumarin ayapanin herniarine methyl umbelliferyl ether chamomile 3d anti-cancer healthy aging essential oils core good odorant ingredient bioactive note flavouring agent natural flavor perfume phytotherapy herbal biological activity aroma nuances scent herb cosmetics bouquet anti-aging perfuming herbalism goodscent aromatherapy pharmacognosy fragrance component smell redolence adjuvants molecule