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chloromethane refrigerant-40 r-40 methyl chloride monochloromethane hcc 40 haloalkane flammable gas crucial reagent industrial chemistry refrigerant organohalogen anthropogenic atmosphere phytoplankton biogenesis emission sugarcane cogeneration interstellar environment silicones methylating agent chlorinating propellant blowing agent polystyrene foam local anesthetic catalyst polymerization herbicide molecule molecular formula skeletal structural structure substance compound component functional group precursor synthesis reaction production 3d