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chlorogenic acid cga ester caffeic quinic intermediate lignin biosynthesis polyphenol hydroxycinnamic acids ferulic coumaric neochlorogenic hibiscus sabdariffa isomer eggplants peaches prunes coffee beans prescription drug food additive 3d contractor flavonoid herb pathway biogenesis cycle path biosynthetic herbalism alternative medicine catabolism herbal alkaloid derivative healthy aging phytochemical plant metabolite enzyme endogenous precursor traditional chinese natural tcm substrate bioprecursor