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chemical formula molecular toxicity synthesis structure structural derivative dihydroxycinnamic acid isomer caffeic hydroxycinnamic precursor urine cynarin propenoic pubchem ferulic quinic dihydroxyphenyl enoic acrylic c9h8o4 chlorogenic antioxidant methyl ester lactone dpph oxidation rosmarinic 3d rendering biochemistry molecule skeletal geometry metabolite metabolism biosynthesis cycle mechanism pathway path catabolism biosynthetic intermediate biogenesis