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beta-terpinene terpinene isomeric monoterpene cardamom marjoram oil natural sabinene terpinolene pinene biosynthesis mevalonate pathway dimethylallyl pyrophosphate dmapp geranyl isopentenyl ipp supplement biological activity bioactive antioxidant anti-cancer anti-aging healthy aging alternative medicine herbal herbal phytochemical phytotherapy plant herb herbalism pharmacognosy pharmacopoeia molecule molecular formula skeletal structural structure 3d