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antirrhinin anthocyanin 3-rutinoside cyanidin antirrhinum majus snapdragon blackcurrant black raspberry litchi common fig anthocyans pigments flavonoid phenylpropanoid pathway supplement antioxidant metabolite anti-cancer anti-aging healthy aging 3d phytotherapy derivative cycle biosynthetic endogenous mechanism herbal nutrient metabolism phytochemicals path substrate intermediate biogenesis catabolism herb precursor plant synthesis bioprecursor enzyme natural biosynthesis