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acrylic acid propenoic acroleic ethylenecarboxylic vinylformic unsaturated carboxylic vinyl group acrolein glycerol substance matter material compound component agent stuff reagent functional precursor synthesis reaction production building block substituents safety tobacco smoke pulmonary edema ld50 acryloyl 2-carboxyethenyl molecule molecular formula skeletal structural structure geometry ball stick copolymer msds iupac nomenclature name cas einecs fema 3d