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tetraphenylporphyrin tpp h2tpp porphyrin cobalt synthesis pyrrole manganese metal complexes sds hemoglobin cytochrome chlorophyll complexation chloroplast 3d rendering chemical organic bioactive biochemistry biomolecule molecule molecular structural structure formula herbal phytochemicals plant metabolite metabolism biosynthesis biosynthetic intermediate substrate precursor derivative bioprecursor metabolic natural macrocyclic heterocyclic heterocycle polycyclic ring nitrogen pigment