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zinc protoporphyrin protoporphyrin ix zpp coordination complexes zinc red-purple red blood cells heme iron lead poisoning iron deficiency sickle cell anemia sideroblastic chronic anemia vanadium exposure erythropoietic protoporphyria combined cancer therapies znpp heme oxygenase structural chemistry treatment anti-cancer anticancer anti-tumor substance matter material compound component agent stuff reagent functional group precursor synthesis reaction production molecule molecular formula skeletal structural structure 3d scientific research organic chemical