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valeric acid propylacetic 1-butanecarboxylic butanecarboxylic pentanoic alkyl carboxylic unpleasant odor valeriana officinalis valerates pentanoates perfumes cosmetics food additives fruity flavors valerian fusel alcohol additive safe ester foodstuffs methyl ethyl pentyl gut microbiome valerate salts substance matter material compound component agent stuff reagent functional group precursor synthesis reaction production molecule molecular formula skeletal structural structure 3d organic chemical