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tiglic acid monocarboxylic unsaturated organic croton oil tiglinic sabadillic cevadic beetle double bond cis-trans isomer flavoring agent perfume odour irritant aroma smell flavor flavour fragrance odor odorant bouquet redolence relish scent goodscent good nuances cosmetics ingredient perfumery perfuming component flavouring adjuvants substance matter material compound stuff synthesis reaction production 3d