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silicristin silychristin silicristina cunila anastatica hierochuntica flavonolignan lipoxygenase prostaglandin synthetase radical scavenger silybum marianum lipoxygenase inhibitor antagonist polyphenol antioxidant hepatoprotective milk thistle seed diastereomer fatty liver non-alcoholic steatohepatitis liver cirrhosis thyroid toxic damage death cap poisoning chronic hepatitis herbal phytochemical phytotherapy plant herb natural herbalism pharmacopoeia herbal medicine alternative molecule molecular formula skeletal structural structure 3d biochemistry biomolecule bioactive biochemical