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pterochromanol furanochromone glycoside chromone 3d monoterpenoid phytochemical intermediate healthy aging skeletal flavonoid herbal metabolism anti-cancer biological activity bioactive molecule mechanism plant biosynthesis herb path pathway parasympathomimetic food additive nutraceutica natural biomolecule coumarin essential oils terpenoid cell cycle ball stick alkaloid antioxidant prescription drug dietary herbal medicine isoflavone catabolism biosynthetic anti-aging phytoalexin metabolite phytotherapy pharmacognosy biochemistry