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prostaglandin b1 pgb1 prostaglandin growth factor transforming phytop heptanoic acid phytoprostanes molecular formula egr1 fatty impurity metabolite prostanoid prostacycline thromboxane lipid mediator eicosanoid prostate 3d rendering chemical bioactive cell biochemistry biomolecule molecule structural skeletal geometry receptor agonist signaling metabolism biosynthesis mechanism pathway path hmdb intermediate precursor synthesis derivative metabolic