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erucic acid monounsaturated omega-9 fatty wallflower brassicaceae rapeseed oil mustard cis-13-docosenoic trans isomer mineral oils surfactants lubricants biodiesel fuel rapeseed malonyl-coa acyl coa dehydrogenase enzyme oleoyl-coenzyme herbal phytochemical phytotherapy plant herb natural herbalism pharmacognosy pharmacopoeia supplement biological activity bioactive nutrient food additive nutraceutica dietary molecule molecular formula skeletal structural structure ball stick cell biology biochemistry biomolecule 3d