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ergine d-lysergic acid amide lsa d-lysergamide convolvulaceae alkaloid derivative ergot ergotism convulsive gangrenous mycototoxin hallucinogen adrenergic receptor modulator ergolines tryptamine alkaloids quinoline fungi fungus turbina corymbosa ipomoea tricolor phytotoxin vasoconstriction migraines parkinson's disease oxytocic dopaminergic antidopaminergic serotonergic antiserotonergic lysergic ergopeptide clavine serotonin biochemistry biomolecule biochemical molecule molecular formula skeletal structural 3d bioprecursor metabolic endogenous