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dihydroxyphenylethylene glycol dopeg metabolite norepinephrine monoamine oxidase ne catecholamine neurotransmitter noradrenaline noradrenergic heart 3d metabolism biosynthesis cycle mechanism pathway path catabolism biosynthetic intermediate biogenesis substrate precursor synthesis derivative bioprecursor metabolic enzyme endogenous contractor human metabolome database hmdb norsteroid mineralocorticoid corticosteroid hormone hormonal therapy replacement endocrine level prohormone analogue