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dihydronormethandrone dhnmt androgen anabolic steroid metabolite normethandrone androgen receptor 3d metabolism biosynthesis cycle mechanism pathway path catabolism biosynthetic intermediate biogenesis substrate precursor synthesis derivative bioprecursor metabolic enzyme endogenous contractor human metabolome database hmdb hormone hormonal therapy replacement function action endocrine level prohormone analogue bioactive cell biochemistry biology biomolecule anabolic-androgenic male