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cadinene essential oil phytochemical cade juniper juniperus oxycedrus isomer bicyclic sesquiterpene stereochemistry bridgehead carbon enantiomer 3d bioactive anti-aging cell path healthy aging metabolite antioxidant geometry parasympathomimetic plant skeletal herbal medicine metabolism mechanism monoterpenoid pharmacopoeia anti-cancer molecular biochemistry prescription drug pathway biosynthesis cycle tcm alternative nutrient herbalism coumarin phytoalexin biological activity alkaloid biomolecule structure catabolism molecule