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bilirubin glucuronide monoglucuronide bilirubin metabolite metabolism biosynthesis mechanism pathway path catabolism biosynthetic intermediate biogenesis substrate synthesis derivative bioprecursor metabolic enzyme endogenous di-glucuronide macrophages phagocytize red blood corpuscles hemoglobin albumin lipoprotein glomerular filtration hepatocyte liver sinusoid endoplasmic reticulum pyrrole rings renal tubules bile pigments urine disease renal dubin–johnson syndrome hepatitis hyperbilirubinemia rotor biliary duct blockage crigler najjar gilbert’s neonate jaundice hemolytic brain damage 3d