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anthocyanidin plant pigment anthocyanin flavylium cation oxonium ion polymethine flavonoid chromenylium grapes blueberries 3-deoxyanthocyanidins luteolinidin liverwort ricciocarpos natans marchantia polymorpha riccia duplex scapania undulata chalcones herbal phytochemical phytotherapy plant herb natural herbalism pharmacognosy pharmacopoeia supplement biological activity bioactive nutrient prescription drug food additive nutraceutica antioxidant anti-cancer anti-aging healthy aging alternative medicine tcm traditional chinese herbal 3d molecule molecular formula skeletal structural structure