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acetaldehyde ethanal acetic aldehyde ethyl acetylaldehyde alcohol dehydrogenase enzyme liver hangover consumption disulfiram carcinogen production tautomerization vinyl alcohol organic synthesis heterocyclic compound acetal derivatives precursor vinylphosphonic acid fermentation alcoholic safety danger toxicity carcinogenicity dna crosslinks alzheimer's disease genetic conditions tobacco smoke plastics substance material component reagent functional group reaction molecule molecular formula skeletal structural structure geometry 3d